Parpan, Switzerland, 11 March 2022

It is happening: Air sensors for everyone, everywhere!

I am currently in the beautiful Swiss village of Parpan, writing this letter right after our 8th ULISSES consortium meeting. The research we are doing in ULISSES is paving the road for future mass-implementation of air quality sensors. Let me summarize our technical achievements this far, by thematic area.
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Henrik Rödjegård, crusader for better air quality

Air quality mapping

If you take one of the Bzzt electrical taxi pods in Stockholm, you might help mapping the air quality of the city. In fact, in collaboration with Bzzt, ULISSES set up an IoT testbed for a network of mobile air quality sensors . We equipped five taxi pods with our carbon dioxide sensors and geotagging, so that they continuously record the air quality at any position. We found that such a small number of sensors provides surprisingly good mapping of the carbon dioxide levels in the city center, thanks to the semi-random movement of the taxi pods. The collected data is useful for a variety of applications. For example, we developed a route planning tool that works as a Google Maps plug-in and identifies the route with the lowest exposure to exhaust gas, based on the real air quality data.
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Henrik Rödjegård, crusader for better air quality
I am currently in the beautiful Swiss village of Parpan, writing this letter right after our 8th ULISSES consortium meeting. The research we are doing in ULISSES is paving the road for future mass-implementation of air quality sensors. Let me summarize our technical achievements this far, by thematic area.

Air quality mapping

If you take one of the Bzzt electrical taxi pods in Stockholm, you might help mapping the air quality of the city. In fact, in collaboration with Bzzt, ULISSES set up an IoT testbed for a network of mobile air quality sensors . We equipped five taxi pods with our carbon dioxide sensors and geotagging, so that they continuously record the air quality at any position. We found that such a small number of sensors provides surprisingly good mapping of the carbon dioxide levels in the city center, thanks to the semi-random movement of the taxi pods. The collected data is useful for a variety of applications. For example, we developed a route planning tool that works as a Google Maps plug-in and identifies the route with the lowest exposure to exhaust gas, based on the real air quality data.

Intelligent sensors

For large-scale implementation, each air quality sensor must provide reliable data during its whole lifetime. However, sensors are not perfect, and they age. In ULISSES, we developed machine learning algorithms for networked Cloud-connected sensors that allow the sensors to stay calibrated with support from their peer or superior sensor friends. Using Cloud intelligence, each sensor can learn from its own and other sensors’ history and self-estimate its own reliability. Moreover, instead of reporting a value as the sensor reading, the sensors provide ranges of likely readings with different probabilities. Such a data representation makes it possible for the sensors to learn from each other and agree on even more confident measurements of the air quality. This work resulted in a number of publications [11, 14], including parts of a PhD-thesis. In the close future, we will see more and more “intelligent” gas sensors that learn from their own history and their friends to provide more reliable data.

Photonic waveguide technology for gas sensors

Today, gas sensors based on infrared spectroscopy are bulky - several cubic centimeters in size - and power hungry. In ULISSES, we aim at realizing chip-integrated gas sensors of just a few cubic millimeters. Such miniaturization is impossible using traditional free-space optics technology because, due to the physics involved sensors become less sensitive the smaller you make them. Instead, we use MOEMS technology, and particularly integrated waveguides, which in general public terms are very tiny optical fibers [16, 17]. Our waveguides have a cross-section smaller than the infrared light they guide. In this way, the light travels along the waveguide partly inside it and partly outside it. This last fraction of light is thus in contact with the gas around the waveguide and it is affected by the gas concentration. Waveguides that are several centimeters long can be fabricated on a very small chip over an area of just a few square millimeters. Until now, we developed and tested all the microfabrication methods [1, 6, 8, 10, 13], including chip-scale packaging [13], required for such micro-optical sensor chips. We recently started the very challenging first fabrication run, where all essential parts of the gas sensor are put together and integrated on the same chip. Just like you, I am eager to see the first prototype at work!

2D materials: Active devices

Optical gas sensors require a light source and a light detector. 2D materials such as graphene and platinum diselenide have unique properties that allow them to convert infrared light into a detectable electric response. In ULISSES, we developed a new graphene photodetector suitable for waveguide integration. It uses electrical bias to form a thermoelectric junction that can efficiently convert the electrons excited by light into an electrical current [4, 9]. Moreover, we developed a new growth technique for the production of high-quality platinum diselenide directly on top of waveguides [5, 7]. The research work on 2D-material photodetectors also enabled us to fabricate and test novel waveguide-integrated infrared thermal light sources.

2D materials: Processing technologies

Typically, the placing of graphene on semiconductor wafers or chips is a manual process that consists in “fishing” the thin graphene layers that are floating like jellyfish in a liquid bath with the target substrate. This is of course not suited for high-quality mass fabrication. In ULISSES, we developed wafer-scale dry transfer processes that result in good coverage with very few cracks, also on surfaces with waveguide topography, and are much better suited for mass production. Finally, we made significant progress in encapsulating graphene to protect it from the environment without damaging it [6].

In conclusion, ULISSES is producing significant advancements on all these fronts to enable the mass implementation of air quality sensors. Every little achievement on this road is part of the puzzle, but it is also a scientific breakthrough in itself, and will find application in many other fields as well.

Henrik Rödjegård and the ULISSES team

References

1.
Vacuum-sealed silicon photonic MEMS tunable ring resonator with an independent control over coupling and phase.
Optics Express 31, 6540 (2023). doi: 10.1364/OE.480219. Archive: Infoscience
2.
Wafer-level hermetically sealed silicon photonic MEMS by Direct Metal-to_Metal Bonding.
in WaferBond’22 Conference of Wafer Bonding for Microsystems, 3D- and Wafer Level Integration (2022). Archive: DIVA
3.
On Data-Driven Self-Calibration for IoT-Based Gas Concentration Monitoring Systems.
IEEE Internet of Things Journal 9, 13848–13861 (2022). doi: 10.1109/JIOT.2022.3144934. Archive:
4.
Graphene waveguide-integrated thermal infrared emitter.
in 2022 Device Research Conference (DRC) 1–2 (IEEE, 2022). doi: 10.1109/DRC55272.2022.9855779. Archive: Zenodo
5.
Two-Dimensional Platinum Diselenide Waveguide-Integrated Infrared Photodetectors.
ACS Photonics acsphotonics.1c01517 (2022). doi: 10.1021/acsphotonics.1c01517. Archive: Zenodo
6.
Wafer-level hermetically sealed silicon photonic MEMS.
Photonics Research 10, A14 (2022). doi: 10.1364/PRJ.441215. Archive: Infoscience
7.
2D materials for future heterogeneous electronics.
Nature Communications 13, 1392 (2022). doi: 10.1038/s41467-022-29001-4. Archive: PubMed
8.
Integration of Two-Dimensional Materials for Electronics and Photonics.
(2022). Archive: DIVA
9.
Intelligent System Designs: Data-driven Sensor Calibration & Smart Meter Privacy.
(2022). Archive: DIVA
10.
Time-Adaptive Expectation Maximization Learning Framework for HMM Based Data-Driven Gas Sensor Calibration.
IEEE Transactions on Industrial Informatics 1–10 (2022). doi: 10.1109/TII.2022.3215960
11.
All-carbon approach to inducing electrical and optical anisotropy in graphene.
AIP Advances 11, 115007 (2021). doi: 10.1063/5.0062521
12.
Hybrid Devices by Selective and Conformal Deposition of PtSe 2 at Low Temperatures.
Advanced Functional Materials 2103936 (2021). doi: 10.1002/adfm.202103936
13.
Plasma-Enhanced Atomic Layer Deposition of Al 2 O 3 on Graphene Using Monolayer hBN as Interfacial Layer.
Advanced Materials Technologies 2100489 (2021). doi: 10.1002/admt.202100489
14.
Correlating Nanocrystalline Structure with Electronic Properties in 2D Platinum Diselenide.
Advanced Functional Materials 2102929 (2021). doi: 10.1002/adfm.202102929
15.
Waveguide-Integrated Photodetectors based on 2D Platinum Diselenide.
in 2021 Device Research Conference (DRC) 1–2 (IEEE, 2021). doi: 10.1109/DRC52342.2021.9467238
16.
Optimizing the Photothermoelectric Effect in Graphene.
Physical Review Applied 15, 054049 (2021). doi: 10.1103/PhysRevApplied.15.054049
17.
Large-area integration of two-dimensional materials and their heterostructures by wafer bonding.
Nature Communications 12, 917 (2021). doi: 10.1038/s41467-021-21136-0. Archive: PubMed
18.
Hidden Markov Model Based Data-driven Calibration of Non-dispersive Infrared Gas Sensor.
in 2020 28th European Signal Processing Conference (EUSIPCO) 1717–1721 (IEEE, 2021). doi: 10.23919/Eusipco47968.2020.9287334. Archive: DIVA
19.
Stacking of Two-Dimensional Materials to Large-Area Heterostructures by Wafer Bonding.
in Conference on Lasers and Electro-Optics SW3F.2 (OSA, 2021). doi: 10.1364/CLEO_SI.2021.SW3F.2
20.
Graphene in 2D/3D Heterostructure Diodes for High Performance Electronics and Optoelectronics.
Advanced Electronic Materials 7, 2001210 (2021). doi: 10.1002/aelm.202001210
21.
Belief Function Fusion based Self-calibration for Non-dispersive Infrared Gas Sensor.
in 2020 IEEE SENSORS 1–4 (2020). doi: 10.1109/SENSORS47125.2020.9278753. Archive: DIVA
22.
Nanoelectromechanical Sensors Based on Suspended 2D Materials.
Research 2020, 1–25 (2020). doi: 10.34133/2020/8748602. Archive: PubMed
23.
On-Chip Dispersion Spectroscopy of CO2 Using a Mid-Infrared Microring Resonator.
in Conference on Lasers and Electro-Optics STh1N.3 (OSA, 2020). doi: 10.1364/CLEO_SI.2020.STh1N.3. Archive: DIVA
24.
Mid-infrared photonic devices for on-chip optical gas sensing.
(KTH Royal Institute of Technology, 2019). http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-261188.
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Hans Martin
Project coordinator
Senseair
Stationsgatan 12,
82471 Delsbo
+46.653.121.29
Kirsten Leufgen
Project manager
SCIPROM
Rue du Centre 70
CH-1025 St-Sulpice
+41.21.694.04.12
This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 825272 (ULISSES).